14–16 Nov 2022
Perimeter Institute for Theoretical Physics
America/Toronto timezone

Stacking Induced Spontaneous Polarization in Rhombohedral MoS2

14 Nov 2022, 10:15
45m
PI/1-100 - Theatre (Perimeter Institute for Theoretical Physics)

PI/1-100 - Theatre

Perimeter Institute for Theoretical Physics

190

Speaker

Ziliang Ye (University of British Columbia)

Description

"The relatively weak van der Waals bond in 2D materials has ushered in a rich new era of stacking engineering. We recently found in rhombohedrally stacked MoS2, a Berry phase contrast between layers can induce an asymmetric interlayer coupling and an out-of-plane spontaneous electrical polarization (1). The polarization direction can be switched via interlayer sliding, forming a new type of ferroelectricity. In addition, we demonstrated that such a polarization can lead to a spontaneous photovoltaic effect without any pn junctions (2). Compared to conventional PV effects, our device shows a similar quantum efficiency with an ultrafast speed and potentially a programmable polarity. The rhombohedrally stacked transition metal dichalcogenides therefore provide a new platform for studying spontaneous polarization at the atomic scale.

(1) Jing Liang, et al, arXiv:2209.06966 (2022).
(2) Dongyang Yang, et al, Nature Photonics, 16, 469–474 (2022)."

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